Production of concrete

 Raw Material

Structural concrete normally contains one part cement to two parts fine mineral aggregate to four parts coarse mineral aggregate, though these proportions are often varied to achieve the strength and flexibility required in a particular setting. In addition, concrete contains a wide range of chemicals that imbue it with the characteristics desired for specific applications. Portland cement, the kind most often used in concrete, is made from a combination of a calcareous material (usually limestone) and of silica and alumina found as clay or shale. In lesser amounts, it can also contain iron oxide and magnesia. Aggregates, which comprise 75 percent of concrete by volume, improve the formation and flow of cement paste and enhance the structural performance of concrete. Fine grade comprises particles up to. 20 of an inch (five millimeters) in size, while coarse grade includes particles from. 20 to. 79 of an inch (20 millimeters). For massive construction, aggregate particle size can exceed 1.50 inches (38 millimeters).
Aggregates can also be classified according to the type of rock they consist of: basalt, flint, and granite, among others. Another type of aggregate is pozzolana, a siliceous and aluminous material often derived from volcanic ash. Reacting chemically with limestone and moisture, it forms the calcium silicate hydrates that are the basis of cement. Pozzolana is commonly added to Portland cement paste to enhance its densification. One type of volcanic mineral, an aluminum silicate, has been combined with siliceous minerals to form a composite that reduces weight and improves bonding between concrete and steel surfaces. Its applications have included precast concrete shapes and asphalt/concrete pavement for highways. Fly ash, a coal-burning power plant byproduct that contains an aluminosilicate and small amounts of lime, is also being tested as a possible pozzolanic material for cement. Combining fly ash with lime (CaO) in a hydrothermal process (one that uses hot water under pressure) also produces cement.
A wide range of chemicals are added to cement to act as plasticizers, superplasticizers, accelerators, dispersants, and water-reducing agents. Called admixtures, these additives can be used to increase the workability of a cement mixture still in the nonset state, the strength of cement after application, and the material's water tightness. Further, they can decrease the amount of water necessary to obtain workability and the amount of cement needed to create strong concrete. Accelerators, which reduce setting time, include calcium chloride or aluminum sulfate and other acidic materials. Plasticizing or superplasticizing agents increase the fluidity of the fresh cement mix with the same water/cement ratio, thereby improving the workability of the mix as well as its ease of placement. Typical plasticizers include polycarboxylic acid materials; superplasticizers are sulphanated melamine formaldehyde or sulphanated naphthalene formaldehyde condensates. Setretarders, another type of admixture, are used to delay the setting of concrete. These include soluble zinc salts, soluble borates, and carbohydrate-based materials. Gas forming admixtures, powdered zinc or aluminum in combination with calcium hydroxide or hydrogen peroxide, are used to form aerated concrete by generating hydrogen or oxygen bubbles that become entrapped in the cement mix.
Cement is considered a brittle material; in other words, it fractures easily. Thus, many additives have been developed to increase the tensile strength of concrete. One way is to combine polymeric materials such as polyvinyl alcohol, polyacrylamide, or hydroxypropyl methyl cellulose with the cement, producing what is sometimes known as macro-defect-free cement. Another method entails adding fibers made of stainless steel, glass, or carbon. These fibers can be short, in a strand, sheet, non-woven fabric or woven fabric form. Typically, such fiber represents only about one percent of the volume of fiber-reinforced concrete.